Abstract
AbstractThe syntheses and physicochemical properties of the three dinitrogen complexes [Mo(N2)2(tdppme)(PMe3)], [Mo(N2)(tdppme)(PMe3)2] and [Mo(N2)2(tdppme)(PMe2Ph)] supported by the tripodal ligand 1,1,1‐tris(diphenylphosphinomethyl)ethane (tdppme) are reported. The complexes are characterized by 31P NMR‐, IR‐ and Raman spectroscopy. The influence of the ligand tdppme on the coordination of PMe3, PMe2Ph, PMePh2, PPh3 and dcpm (bis(dicyclohexylphosphine) is investigated and compared to earlier results involving dppm and dmpm as co‐ligands.
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