Molten-salt-induced interpenetrated meso/macro porous structural hard carbon derived from chitosan for enhanced potassium ions storage

Abstract

Hard carbon materials are commonly used as anode materials for environmentally friendly potassium-ion energy devices due to excellent development prospects. However, the poor conductivity and unsatisfactory rate performance of hard carbon limit their development. Herein, chitosan was chosen as the carbon precursor to prepare interpenetrated meso/macro-porous structural hard carbon (PC) formed by the template agent NaCl in the molten state at high temperature as the anode for potassium-ion batteries. PC with a high content of pyridinic N, pyrrolic N, and CO bonds can provide a high reversible capacity of 280.1 mAh g−1 at the current density of 0.05 A g−1, and show an improved rate performance of 173.8 mAh g−1 at 1.0 A g−1. Galvanostatic charge/discharge (GCD) curves do not exhibit an obvious plateau, indicating that surface adsorption is dominant in the potassium ions storage mechanism. The high K+ diffusion coefficient indicates that the interconnected meso/macro structure allows potassium ions to diffuse faster in PC. Therefore, using activated carbon (AC) as the cathode and PC as the anode, a potassium-ion hybrid capacitor (PIHC) is fabricated, which can achieve an energy density of 130 Wh kg−1 at the current density of 0.05 A g−1 and an energy density of 62 Wh kg−1 at 1.0 A g−1.