Abstract

The crystallographic and magnetic phase transitions observed in TbP${\mathrm{O}}_{4}$ and TmAs${\mathrm{O}}_{4}$ are described phenomenologically. A symmetry-adapted spin Hamiltonian, involving various dipolar and quadrupolar interactions, is constructed and treated in the molecular-field approximation. One or two phase transitions are found according to the values of the interaction parameters, and it is shown that the crystallographic distorsion in the paramagnetic distorted phase is monoclinic. The results are interpreted in terms of the Pytte and Stevens model for rare-earth vanadates.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.