Abstract
The role played by different anions (XF6− (X = P, As, Sb), BF4−) on the connectivity of coordination networks formed by a combination of different silver salts and an organic tecton based on piperazine bearing two pyridine units has been studied in the crystalline phase by X-ray diffraction on single crystal. All four weakly coordinating anions lead to the formation of analogous 2-D coordination networks. For the isostructural anions XF6− (X = P, As, Sb) the crystals are isomorphous.
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