Abstract
According to the data of IR spectroscopy, dielcometry, and B3LYP/6-31G* quantum-chemical calculations, trifluoromethanesulfonamide homoassociates in weakly basic protophilic media are converted into 2 : 1 solvate H-complexes. Cyclic trifluoromethanesulfonamide dimer decomposes in heteroassociate with dioxane with a composition of 1 : 3. Cyclic trifluoromethanesulfonamide dimer with dioxane forms a 1 : 4 H-complex with bifurcated (three-center) hydrogen bond involving the bridging hydrogen atom of the NH group (NH⋯O).
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