Molecular structure and vibrational spectra of trimethylarsenite

Abstract

The molecular structure and vibrational spectra of trimethylarsenite were studied by gas phase electron diffractometry and IR and Raman spectroscopv. The configuration of the O-methyl groups with respect to the lone electron pair of the arsenic atom is established to be close to gosh-gosh-trans. The main geometrical parameters are: bond lengths (ra, A) As-O 1.780, C-0 1.451, and C-H 1.101; bond angles (deg) As-O-C 115.0, O-As-0 99.5, and O-C-H 115.3. The experimental IR and Raman spectra were obtained for pure liquid and CCl4 solution. The frequencies and forms of normal vibrations were calculated.