Molecular structure and ion exchange of amidoximated cellulosic materials

Abstract

Modification of lignocellulosic materials, e.g., cotton stalks, bagasse, and rice straw, by incorporation of amidoxime group for ion exchange is investigated. The uptake of metal ions Cu, Cr, Ni, and Fe by these modified lignocellulosic materials is measured. Amidoximated bagasse has higher efficiency toward metal ions uptake than amidoximated cotton and rice straw. The effect of different variables, e.g., metal ion concentration, temperature of metal ion solution, and time of steeping, on the efficiency of the amidoximated (bagasse raw material, unbleached bagasse, and bleached bagasse) ion exchangers toward metal ions uptake is tested. The molecular structure of the prepared amidoxime from bagasse and its pulps is studied by using infrared spectroscopy. New bands appeared at 1661 and 916 cm−1 in the spectra of amidoximated bagasse and its pulps ion exchangers due to the formation of CN and NOH groups. The thermal properties of these ion exchangers is also studied. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 303–311, 2006