Molecular scale assessment of defluoridation of coal-mining wastewater by calcined Mg/Al layered double hydroxide using 19F solid-state NMR, XPS, and HRTEM.

Abstract

Calcination is an effective way to improve the F- adsorption capacity of layered double hydroxide (LDH) materials, however, a molecular scale understanding of the enhanced defluoridation capability of calcined LDHs (CLDH) is lacking. This study investigated the mechanisms of F- adsorption by CLDH using 19F solid-state NMR, X-ray photoelectron spectroscopy (XPS), and high-resolution TEM. Under calcination process, LDH underwent three periods: surface dehydration below 200°C, structural dehydroxylation at 200-400°C, and release of interlayer carbonate groups above 400°C. Additionally, XPS and XRD characterization showed that CLDH could not recover to the original structural symmetry even after rehydration and reconstitution. The F- affinity was greatly enhanced for the calcined LDH, especially at high pH. At pH 10, the adsorption capacity could reach 22.0mgF-/g for CLDH (500°C calcined), about 6 times larger than that of LDH. The XRD analyses revealed that the F-adsorbed CLDH had a poorer crystalline degree as the calcination temperature increased, consistent with the TEM observation of abundant defects and Mg/Al oxides on the CLDH sheets. 19F solid-state NMR spectra of the CLDH after F- adsorption showed that the formation of surface Al-F is the predominant F- adsorption mode at pH 7, whereas the Mg-F local coordination mode is the pronounced F- adsorption mechanism under alkaline conditions (pH 10). The present study provided a comprehensive understanding of CLDH in F- adsorption and suggested that calcination is a promising treatment for promoting the efficacy of polluted anion scavenging.