Molecular resolution imaging ofC60 on Au(111) by non-contact atomic force microscopy

Abstract

Non-contact atomic force microscopy (NC-AFM) was used to study thin films ofC60 on Au(111). After observing the Au(111) reconstruction, 2–3 monolayers ofC60 were deposited onto the Au surface. The close-packedC60 surface was imaged by NC-AFM with molecular resolution. Enhanced corrugation and a stretchingof the C60 lattice were observed at step edges. Based on a calculation of the force required todisplace an edge molecule, it is proposed that the edge effects are a result oftip-induced displacements of edge molecules. While imaging small clusters ofC60, some molecules were removed, leading to structural rearrangements of the clusters.