Abstract

Reorientational and angular momentum correlation times τ c and τ J for CCl 4 and CS 2 in alkanes have been derived from 13C spin-spin relaxation times of CCl 4 and 33S linewidths of CS 2. In contrast with neat liquids, molecular reorientation does not obey J-diffusion, but tends towards M-diffusion in large solvents.

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