Abstract
Molar Kerr constants (×10–12) are reported for nitrobenzene (938), 1,3,5-trinitrobenzene (39·1), nitromesitylene (727), 2,4,6-trinitrotoluene (146), trinitromesitylene (-23·0), 1,4-dichloro-2-nitrobenzene (522), mesitylene (13·5), and durene (20·2), as solutes in benzene, and for toluene (13·7), mesitylene (11·5), and hexamethylbenzene (18·4) as solutes in carbon tetrachloride. The polarisability tensor specifications are derived for certain basic structural groups and used to calculate the anisotropic polarisabilities of the C–NO2 group in various environments. The results are shown to be generally in accord with predictions based on the operative electromeric and steric effects.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.