Abstract
Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [PdII (en)] (en=ethylenediamine) into a unique M15 L6 hexahedral coordination capsule (see X-ray structure). The capsule can encapsulate/exchange organic guests reversibly through the clefts at the nonbinding sites of the capsule.
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