Abstract
The fine features of the Auger valence band spectra of TiO and TiO 2 have been related to transitions arising from oxygen 2s and titanium 3d, 4s molecular orbitals. The Auger bands investigated include the L III, M 1N 1, L IIIM 1M 4,5, L IIIM 2,3N 1, and L IIIM 2,3, M 4,5 transitions. The N( E) valence band spectra have been unfolded and the resulting components correlated with X-ray emission data and a molecular orbital (MO) model. Differences in spectral shapes are shown to be linked with differences in the density of state of oxygen—titanium molecular orbitals.
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