Molecular Optomechanics in the Anharmonic Cavity-QED Regime Using Hybrid Metal–Dielectric Cavity Modes

Abstract

Using carefully designed hybrid metal-dielectric resonators, we study molecular optomechanics in the strong coupling regime ($g_{\rm }^2/\omega_m {>} \kappa$), which manifests in anharmonic emission lines in the sideband-resolved region of the cavity-emitted spectrum ($\kappa{<}\omega_m$). This nonlinear optomechanical strong coupling regime is enabled through a metal-dielectric cavity system that yields not only deep sub-wavelength plasmonic confinement, but also dielectric-like confinement times that are more than two orders of magnitude larger than those from typical localized plasmon modes. These hybrid metal-dielectric cavity modes enable one to study new avenues of quantum plasmonics for single molecule Raman scattering.