Molecular interactions in binary mixtures of 1-butoxy-2-propanol with alcohols at different temperatures: A thermophysical and spectroscopic approach

Abstract

This paper reports densities (ρ) and speeds of sound (u) of 1-butoxy-2-propanol CH3(CH2)3OC3H6OH, 1-propanol CH3(CH2)2OH, 2-propanol (CH3)2CHOH, 1-butanol CH3(CH2)3OH and 2-butanol CH3CH2CH(OH)CH3 and their binary mixtures with 1-butoxy-2-propanol as a common component, measured at T=(293.15, 298.15, 303.15, 308.15 and 313.15)K over the entire composition range. These experimental values of density and speed of sound were used to calculate the values of excess molar volumes, VmE, deviations in molar isentropic compressibility Δκs and deviations in speed of sound uD. Further, experimental densities were used to estimate apparent molar volumes Vϕ,i, partial molar volumes V‾m,1, excess partial molar volumes V‾m,1E and their limiting values at infinite dilution Vϕ,i∞, V‾m,i∞ and V‾m,iE,∞ respectively. The variations observed in these properties, with composition and temperature, are discussed in terms of molecular interactions due to physical and chemical effects between the unlike molecules of the binary mixtures. These properties, especially excess functions, are found to be quite sensitive towards the intermolecular interactions in liquid mixtures. These excess functions and deviations have also been correlated using Redlich–Kister type polynomial equation by the method of least-squares for the estimation of the binary coefficients and the standard errors. FT-IR studies of these mixtures are also reported.