Abstract
Ultrasonic speed (u), density (d) and viscosity (η) of caffeine in aqueous solutions of potassium chloride, sodium chloride, magnesium chloride and calcium chloride have been measured at 308.15 K. From these data, thermodynamic interaction coefficient, isentropic compressibility (β s ), intermolecular free length (L f ), apparent molar volume (Φ v ), relative association (R A ) and acoustic impedance (Z) have been computed. All the derived parameters are correlated with the molar composition of solutions. Depending on the molecular interactions and the nature of the solutions show the change in structure of solvent when solute is added to it. The viscosity coefficients A and B of Jones-Dole equation have been determined and employed to throw light on the mechanism of solute-solute and solute-solvent interactions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zenodo (CERN European Organization for Nuclear Research)
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
