Abstract

AbstractThe effect of a solid wall on Poiseuille flow of ultra thin film has been simulated by molecular dynamics for a simple Lennard‐Jones fluid. Results showed that the velocity profile and flow are consistent with the prediction of the Stokes equations when the film thickness is considerably greater than the molecular ‘diameter’; that Poiseuille or hydrodynamic flow will be blocked by the solid walls, and the effective viscosity will increase as the film thickness corresponds more closely to only a few molecular diameters; and that when the film thickness is reduced to just the molecular diameter, the fluid molecules between the walls will be solidified or crystallised, and the Poiseuille flow will vanish. This may be one of the mechanisms of transition from hydrodynamic to boundary lubrication.

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