Abstract
High-energy-density materials in which cycloalkane hydrogens (cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane, and cyclooctane) were replaced with -N-NO2 and –NO functional groups were designed and evaluated with regard to their explosive characteristics by using density functional theory calculations in combination with the Kamlet-Jacobs equations and an atoms-in-molecules analysis. Improved detonation properties with a higher sensitivity than conventional explosives such as 1,3,5-trinitro-1,3,5-triazinane and 1,3,5,7-tetranitro-1,3,5,7-tetrazocane were predicted. Interestingly, NO-substituted structures showed substantial detonation properties with very low sensitivities. This method of substituting –NO groups on cycloalkanes supplies a firm basis for further studies on the design of new explosives. Moreover, the newly found structures may be promising candidates for developing primary explosives.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.