Molecular design for stabilizing a blue phase III and electro‐optical switching in the blue phase

Abstract

Abstract— The molecular design of a liquid crystal to stabilize a blue phase III (BPIII) is reviewed, and the electro‐optical switching with a response time on the order of 10−2 sec for BPIII exhibited by a novel chiral liquid crystal is reported. Binaphthyl derivatives and T‐shaped compounds are presented, and the structure‐property correlations of the chiral compounds are discussed. Two origins of the twisting power of the compounds, i.e., their inherent molecular chirality and the chirality‐induced twist conformation, play an important role in the appearance of the BPIII. Furthermore, BPIII was also induced in some binary mixtures of a host nematic liquid‐crystal possessing molecular biaxiality and a conventional chiral compound. The electro‐optical switching in the BPIII is attributed to an electric‐field‐induced phase transition between the BPIII and nematic (N) phases. BPIII is on the microscopically twisted nematic order, but is macroscopically isotropic. Therefore, the present technology can offer a pronounced black state in the BPIII without surface treatment and a homogeneous bright state in the induced N phase.