Abstract

Abstract. Atmospheric aerosol samples of PM2.5 and PM10 were collected during the wet and dry seasons in 2011 from a rural site in Tanzania and analysed for water-soluble dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls, and fatty acids using a gas chromatography/flame ionization detector (GC/FID) and GC/mass spectrometry. Here we report the molecular composition and sources of diacids and related compounds for wet and dry seasons. Oxalic acid (C2) was found as the most abundant diacid species followed by succinic and/or malonic acids whereas glyoxylic acid and glyoxal were the dominant ketoacid and α-dicarbonyl, respectively in both seasons in PM2.5 and PM10. Mean concentration of C2 in PM2.5 (121 ± 47 ng m−3) was lower in wet season than dry season (258 ± 69 ng m−3). Similarly, PM10 samples showed lower concentration of C2 (169 ± 42 ng m−3) in wet season than dry season (292 ± 165 ng m−3). Relative abundances of C2 in total diacids were 65% and 67% in PM2.5 and 65% and 64% in PM10 in the wet and dry seasons, respectively. Total concentrations of diacids (289–362 ng m−3), ketoacids (37.8–53.7 ng m−3), and α-dicarbonyls (5.7–7.8 ng m−3) in Tanzania are higher than those reported at a rural background site in Nylsvley (South Africa) but comparable or lower than those reported from sites in Asia and Europe. Diacids and ketoacids were found to be present mainly in PM2.5 in both seasons (total α-dicarbonyls in the dry season), suggesting a production of organic acids from pyrogenic sources and photochemical oxidations. Averaged contributions of total diacids to aerosol total carbon were 1.4% in PM2.5 and 2.1% in PM10 during wet season and 3.3% in PM2.5 and 3.9% in PM10 during dry season whereas those to water-soluble organic carbon were 2.2% and 4.7% in PM2.5 during wet season and 3.1% and 5.8% in PM10 during dry season. The higher ratios in dry season suggest an enhanced photochemical oxidation of organic precursors probably via heterogeneous reactions on aerosols under strong solar radiation. Strong positive correlations were found among diacids and related compounds as well as good relations to source tracers in both seasons, suggesting a mixed source from natural biogenic emissions, biomass burning, biofuel combustion, and photochemical production.

Highlights

  • Earth SystemLow molecular weight dicarboSxycliicenaccides,sketoacids and in PM10 in the wet and dry seasons, respectively

  • Size distributions and average molecular compositions of diacids, ketoacids, α-dicarbonyls and fatty acids in wet and dry seasons are shown in Figs. 2 and 3

  • We found that concentration of terephthalic acid (tPh) acid in PM2.5 is similar to that reported from Sapporo but is lower than those from Chennai and Nainital. tPh could be produced from open burning of solid waste (Simoneit et al, 2005; Kawamura and Pavuluri, 2010), which occurs commonly in Tanzania

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Summary

Introduction

Low molecular weight dicarboSxycliicenaccides,sketoacids and in PM10 in the wet and dry seasons, respectively. Studies have reported that dicarboxylic acids and related compounds are ubiquitously present in the atmospheric aerosols from various environments in continental rural and urban (Limbeck et al, 2001, 2005; Kerminen et al, 2000; Kawamura and Yasui, 2005; Ho et al, 2006; Hsieh et al, 2008; Hyder et al, 2012; Wang et al, 2012), coastal and remote marine (Kawamura and Sakaguchi, 1999; Mochida et al, 2007; Rinaldi et al, 2011), and polar sites (Kawamura et al, 1996b, 2010, 2012; Narukawa et al, 2003). We report for the first time the molecular composition of dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls and fatty acids in aerosols from a rural background site in Tanzania, East Africa and discuss their size distributions, seasonal variations, sources and formation pathways

Site description
Aerosol sampling
Chemical analysis
Meteorology and air mass trajectories
Results and discussion
Temporal variations of diacids and related compounds
C3 C4 iC4 iC5 M ωC2 ωC3 ωC4 ωC9 Gly
Summary and conclusions
Full Text
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