Abstract
The new rhenium-copper heteronuclear complex [NEt4]3[ReS4C3Cl5]2, was obtained as black crystals in 65% yield, from the reaction of [NEt4[[ReS4], [NEt4][CuCl2], and [NEt4][Cl] at - 20°C in acetone, while at room temperature without additional chloride [NEt4]2[ReS4Cu3Cl4]1 crystallized as black crystals in 60% yield. Crystal data for2: space group Pl,a=10.331(4) A,b=14.261(2) A,c= I4.458(3) A, α=78.55(1)°, β=81.83(3)°, γ=83.66(3)°,Z=2, 6480 reflections;R=0.058. For1: space group C2/c,a=20.969(5)A,b=12.955(5)A,c=22.827(8)A, β=91.16(2)°, Z=8, 3208 reflections,R = 0.052, The geometry of2 can be viewed as restllting from the opening of the cubane-like structure of1.
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