Abstract
The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3] (trans-Ru · 0.5CDCl3), are presented. The molecule of trans-Ru · 0.5CDCl3 crystallizes in the triclinic sp. gr. $$P\bar {1}$$ with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.
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