Abstract

The title compound has been studied by an X-ray structure analysis (a CAD-4 diffractometer, λMoKα, graphite monochromator, ω/2θ scan, 2θmax, direct methods, 884 reflections R=0.0416). The crystals are orthorhombic with a=20.326, b=8.828, c=7.3872 A, V=1325.6 A3, and Z=4. C8H18B9N, space group Pnam, dcalc=1.130 g/cm3, dexp=1.130 g/cm3. The compound is a molecular complex. The main feature of its crystal structure is the coexistence of two asymmetric mirror isomers which have the same pyridine cycle and the same atoms of the carborane skeleton (excluding C7, H7C, and H34). The methyl group has a disordered orientation in two positions. The complexes are linked by van der Waals interactions.

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