Modulation of the emission spectrum of rare-earth ions using inverse-designed photonic crystals cavities.

Abstract

Rare-earth elements play an indispensable role in the optical communication and laser industries, due to their superior luminescent properties. Nevertheless, the selective enhancement and suppression of different emission bands during energy level transitions for multi-band emitting rare-earth ions presents a significant research challenge, which we aim to address. This study explores the potential of leveraging an inverse-designed dual-cavity photonic crystals structure to manipulate the emission spectrum, thereby facilitating the augmentation or suppression of distinct emission bands. We utilized a convolutional neural network model to establish the relationship between geometric parameters and the local density of states, forecasting the optimal cavity geometry parameters for achieving the desired modulation outcomes. This paper delineates the neural network's generalization capabilities, along with the modulation efficacy of the dual-cavity configuration, both confirmed through numerical validation. Our findings highlight the modulatory capacity of Dy3+ ions, which exhibit three emission spectrum in the visible range, to achieve pure color light emission within the devised cavity structure. Notably, our approach yielded enhancements of up to 2.79-fold and 2.81-fold in pure yellow and red light emissions respectively, compared to free space emissions. The single-sided emission enhancement reaches 16.28-fold for yellow light and 30.79-fold for red light. This emphasizes the transformative potential of this methodology in crafting rare-earth-based luminescent materials with meticulously engineered emission attributes.