Abstract
By combining a halogen bonding donor of 1,4-diiodotetrafluorobenzene (1,4-DITFB) or 1,2-diiodotetrafluorobenzene (1,2-DITFB) with 4-benzoyloxy-2,2,6,6-tetramethyl-piperidine-1-oxy free radical (BTEMPO, 1), two novel cocrystals, BTEMPO·1,4-DITFB (2) and BTEMPO·2(1,2-DITFB) (3), featuring a one-dimensional (1D) zigzag chain and a cyclic tetrameric structure, respectively, were constructed via halogen bonding. Furthermore, by tuning the halogen bonding between BTEMPO and halogen bonding donors, the packing modes of organic free radicals in both 2 and 3 are successfully modulated to result in side-by-side 1D mode in 2 and head-to-head dimer manner in 3. Magnetic studies reveal that in all compounds the organic radicals are antiferromagnetically coupled; however, the magnetic coupling in 2 and 3 is stronger than that in 1, indicating the modulating effect of halogen bonding on magnetic properties that are further confirmed by quantum chemistry calculations.
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