Abstract

The development of efficient electrocatalyst is one of the effective ways to speed up the efficiency of water electrolysis. In this work, we prepared a nested-like Ce-doped CoP nanowires catalytic material on carbon cloth by simple hydrothermal and phosphating methods. After adjusting the doping ratio of Ce, the doping ratio (Ce/W = 6 %) with the best performance is obtained and named as Ce-CoP NWs/CC. The Ce-CoP NWs/CC exhibits preeminent electrocatalytic activity with low overpotentials with 80 and 290 mV at 10 mA cm−2 for HER and OER, respectively. Moreover, the Ce-CoP NWs/CC electrocatalyst also exhibits excellent electrochemical performance in overall water splitting with a low voltage of 1.506 V at 10 mA cm−2, outperforming many reported electrocatalysts. This work provides a feasible electrocatalytic material for the introduction of rare earth elements into water electrolysis.

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