Abstract
Abstract N,N´-dimethyl-N,N´-dioctyl-2,(2´-hexyloxyethyl) malonamide (DMDOHEMA) has been synthesized by a relatively simpler route with a better yield than the conventional procedures for the synthesis of pentaalkyl substituted diamides. The proposed route replaces the use of acid chlorides and brominating agents (corrosive in nature) by acid diester and p-toluene sulphonyl (tosyl) chloride, respectively. The later easily replaces hydrogen from primary OH group of the 3-oxanonyl side chain and relatively less corrosive. The synthesized product has been tested for the extraction behavior of 241Am, Np, Pu as pure tracers as well as under Pressurized Heavy Water Reactor (PHWR) Simulated High-Level Waste (SHLW) conditions. The stoichiometries of extracted species of Np(IV), Pu(IV), and Am(III) from 3 M HNO3 using varying concentrations of DMDOHEMA in n-dodecane has been determined. The effect of the nature of mineral acid (viz. HCl, HNO3, and HClO4) on the extraction of Am(III) has also been investigated employing DMDOHEMA and N,N´-dimethyl-N,N´-dibutyl-tetradecyl malonamide (DMDBTDMA) as extractants and explained in terms of the aggregation behavior of diamides. The performance of DMDOHEMA has been evaluated vis-à-vis other proposed extractants for actinide partitioning under PHWR-SHLW conditions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
