Modified Natural Diatomite with Various Additives and Its Environmental Potential.

Abstract

Diatomite has recently been the subject of intensive scientific research aimed at its extensive use in industry, breeding and agriculture. The only active diatomite mine is in Jawornik Ruski, in the Podkarpacie region of Poland. Chemical pollution in the environment, including that from heavy metals, poses a threat to living organisms. Reducing the mobility of heavy metals in the environment through the use of diatomite (DT) has recently gained much interest. More effective immobilisation of heavy metals in the environment with DT, mainly through the modification of its physical and chemical properties by various methods, should be applied. The aim of this research was to develop a simple and inexpensive material showing more favourable chemical and physical properties compared with unenriched DT in terms of metal immobilisation. Diatomite (DT), after calcination, was used in the study, considering three grain fractions, i.e., 0-1 mm (DT1); 0-0.5 mm (DT2) and 5-100 µm (DT3). Biochar (BC), dolomite (DL) and bentonite (BN) were used as additives. The proportion of DTs in the mixtures amounted to 75%, and of the additive, 25%. The use of unenriched DTs after calcination poses the risk of releasing heavy metals into the environment. Enrichment of the DTs with BC and DL resulted in a reduction or absence of Cd, Zn, Pb and Ni in aqueous extracts. It was found that for the specific surface area values obtained, the additive used for the DTs was of crucial importance. The reduction in DT toxicity has been proven under the influence of various additives. The mixtures of the DTs with DL and BN had the least toxicity. The obtained results have economic importance, as the production of the best quality sorbents from locally available raw materials reduces transport costs and thus the environmental impact. In addition, the production of highly efficient sorbents reduces the consumption of critical raw materials. It is estimated that the savings from producing sorbents with the parameters described in the article can be significant in comparison with popular competitive materials of other origins.