Abstract

Modified methods to synthesize, 1,8-bis[2-diphenylphosphoryl)phenoxy]-3,6-dioxaoctane phosphoryl podand (L), an effective complexing agent for the lithium cation, is reported. The possibility to use the phase-transfer catalysis and microwave irradiation is shown. The crystal structure of coordination complex [LiL]ClO4·2C6H6 is determined by X-ray diffraction analysis.

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