Abstract
BackgroundRemoval of mercury from aqueous environment has been highly regarded in recent years and different methods have been tested for this purpose. One of the most effective ways for mercury ions (Hg+2) removal is the use of modified nano porous compounds. Hence, in this work a new physical modification of mesoporous silica (SBA-15) with 1, 3, 5 (Trithiane) as modifier ligand and its application for the removal of Hg+2 from aqueous environment has been investigated. SBA-15 and Trithiane were synthesized and the presence of ligand in the silica framework was demonstrated by FTIR spectrum. The amounts of Hg+2 in the samples were determined by cold vapor generation high resolution continuum source atomic absorption spectroscopy. Also, the effects of pH, stirring time and weight of modified SBA-15 as three major parameters for effective adsorption of Hg+2 were studied.ResultsThe important parameter for the modification of the adsorbent was Modification ratio between ligand and adsorbent in solution which was 1.5. The results showed that the best Hg+2 removal condition was achieved at pH = 5.0, stirring time 15 min and 15.0 mg of modified adsorbent. Moreover, the maximum percentage removal of Hg+2 and the capacity of adsorbent were 85% and 10.6 mg of Hg+2/g modified SBA-15, respectively.ConclusionsTo sum up, the present investigation introduced a new modified nano porous compound as an efficient adsorbent for removal of Hg+2 from aqueous environment.
Highlights
Mercury as a kind of heavy metal is present in industrial wastewater such as chemical industry, mining, refining petrochemical and a wide variety of industrial activities [1,2]
Trithiane due to its ability to adsorb Hg+2 has been chosen as the ligand for the modification of SBA-15 resulting in a new adsorbent for removing Hg+2 from aqueous environment and the Batch method was applied in order to examine the capability of this new adsorbent
Synthesis of SBA-15 SBA-15 preparation was based on the procedure in the literature [34]. 2.0 g of triblock copolymer P123 (EO20PO70EO20) was dissolved in 60.0 g of 2 M Hydrochloric acid (HCl) aqueous solution stirred at 40°C
Summary
The important parameter for the modification of the adsorbent was Modification ratio between ligand and adsorbent in solution which was 1.5. The maximum percentage removal of Hg+2 and the capacity of adsorbent were 85% and 10.6 mg of Hg+2/g modified SBA-15, respectively
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