Modified materials based on layered minerals as ameliorants for the remediation of podzol in the industrial barren

Abstract

Layered silicates, such as serpentine and vermiculite, have properties that make it possible to use materials based on them as components of environmental technologies. The possibility of soil remediation in industrially contaminated area, formed due to the long-term exposure to emissions from copper-nickel production (Monchegorsk, Murmansk region), was studied. Two materials were used as ameliorants in our study: expanded vermiculite and granular serpentine sorbent, a waste after using the purification technology of highly concentrated solutions from metals. These materials have a high sorption activity to several metals, a high specific surface area, the ability to retain moisture, and are available in quantities sufficient to work on the remediation of large areas. A study of the physicochemical properties of industrially polluted soil and ameliorants, direct phytotoxicity testing of podzol and its mixtures with expanded vermiculite and the serpentine sorbent (test plants - common oat Avna satva L. and red clover Trifolium pratnse L.) were carried out. The study results showed that the proposed materials were effective additives for increasing the pH of acidic soil, sorption and precipitation of Al and potentially toxic metals - Cu, Ni, Pb, Fe, and improving the soil hydrophysical and agrochemical characteristics. A positive response of test plants to the introduction of ameliorants into industrially contaminated soil was noted.