Modified coal char materials with high rate performance for battery applications

Abstract

Global energy consumption has been rising since the early 2000s, and most of the energy supply still comes from burning fossil fuels. Considering the detrimental environmental impacts of fossil fuels, such as CO2 emissions, it is crucial to develop clean energy technologies, such as storage devices that can advance long-term reversible and sustainable energy resources. In this work, we demonstrate the direct use of coal char in anodes tailored for both lithium-ion and sodium-ion batteries. The findings show that acid treatment followed by high-temperature argon annealing results in coal char particles with the desired porous structure, surface properties, and turbostratic nanodomains that deliver high reversible capacity and maintain good electrochemical performance at high rates up to 10C. Long-term cycling stability for 500 cycles can be achieved in cells comprising NMC cathodes at 1C with 73.2% capacity retention. This study sheds light on potential energy storage use cases for coal char outside its traditional utilization.