Modified carbon materials for high-rate EDLCs application

Abstract

Porous carbon materials, such as activated carbon and activated carbon aerogel, were modified chemically by using a surfactant sodium oleate to improve their specific capacity for high-rate electrochemical double layer capacitors (EDLCs) application. Main impacting factors have been examined for surface modification of activated carbon. Specific capacity can be improved significantly by the surface modification. The enhancement in specific capacity is mainly attributable to improvement in wettability of carbon materials, resulting in a higher usable surface area and a smaller internal resistance. The effects from surface modification become more marked at higher discharge rates, and a much higher energy density can be achieved for the modified carbon materials. In addition, the modified carbon materials possess comparable cycle stability to the original carbon.