Modification to the DRASTIC framework to assess groundwater contaminant risk in rural mountainous catchments

Abstract

Mountainous headwater catchments are safeguards of quality groundwater and hence require special protection against contamination by anthropogenic sources. However, methods currently handling contamination risk fail to produce reliable results in mountainous watersheds because they overlook the influence of downhill flows and contaminant transport in the validation process. To overcome this difficulty, a new model based on so-called “concentration profiles” is presented that combines the DRASTIC framework for evaluation of intrinsic vulnerability, the categorization of land uses for evaluation of specific vulnerability to nitrate and Processing Modflow graphical user interface for simulation of nitrate transport. This model was tested in a mountainous region of Northern Portugal. The risk of groundwater contamination by nitrate was generally classified as moderate. The risky areas are regions used for agriculture and livestock production. These activities have raised nitrate concentrations of spring water (15–25 mg·L−1) downstream the risky areas. The Modflow simulations linked the risky areas (contaminant sources) to actual nitrate plumes (contaminant sinks) and modeled nitrate distributions at specific groundwater travel times. Winter plumes could be simulated for the 1-year stress period, and hence are flushable in a short time span. Spring and summer plumes could only be explained by contaminant transport during 10–20 years. In these cases, even if contaminant sources were immediately neutralized, the washout of nitrate would take decades. These results may hold back the fulfillment of sustainable development goals related to water and sanitation until 2030, and hence deserve reflection by water planners and policy makers. The modeling exercise provided extra evidence that safeguarding the catchment headwater is the keystone of groundwater quality protection in mountainous catchments. Therefore, application of this modified DRASTIC to other mountainous areas may not need to resort to Processing Modflow. The study comprises the main paper (this paper) and a MethodsX companion paper.