Modification of recycled cement with phosphogypsum and ground granulated blast furnace slag

Abstract

Unmodified thermal-activated recycled cement (RC) paste has unfavorable properties like fast setting. This paper intends to modify RC by adding phosphogypsum (PG) and ground-granulated-blast-furnace-slag (GGBS). A comprehensive experimental program combining isothermal calorimetry, mechanical tests, TG, XRD, MIP, 29Si NMR and SEM of modified RC (PG-GGBS-modified-recycled-cement) pastes was conducted. The results show that GGBS and PG not only effectively modified the setting time but also contributed to a more compact skeleton. The final setting time was extended from 12 mins to 84 mins. The 28d and 90d compressive strength reached 29.8 and 36.9 MPa, increaseing by 21.1 % and 39.9 %, respectively. It is shown that PG acted as a sulfate excitation to the active Al2O3 in the GGBS and RC to generate AFt. Rehydrated C-S-H gel could both wrap and protect the CaSO4·2 H2O crystals and crystalline contact points, and effectively filled the pores of the hardened paste, thus promoting the generation of C(-A)-S-H and Ca5(SiO4)2(OH)2. The rehydration of modified RC was associated with a remarkable amount of AFt and AFm intergrowing with the reformed C-S-H gel and generating a compact network skeleton.