Abstract

Modification of isotactic polypropylene (iPP) film was carried out by grafting of acrylic acid (AA) onto its backbone using supercritical (SC) CO2 as a solvent and swelling agent. The iPP film was impregnated with the monomer AA and benzoyl peroxide initiator using SC CO2 at 308.15 K, followed by thermal polymerization of AA within SC CO2-swollen iPP film, resulting in iPP-g-PAA composites. The degree of grafting can be controlled by variation of the soaking time, pressure, concentrations of monomer and initiator in the fluid phase, reaction temperature, and time. The morphology and structure of the products were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, differential scanning calorimetry, and wide angle X-ray diffraction.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.