Abstract
Simple nanoporous alumina matrix modification procedure, in which the electrically highly insulating alumina barrier layer at the bottom of the pores is replaced with the conductive layer of the gold beds, was described. This modification makes possible the direct electron exchange between the underlying aluminum support and the redox species encapsulated in the alumina pores, thus, providing the generic platform for the nanoporous alumina sensors (biosensors) with the direct amperometric signal readout fabrication.
Highlights
Porous anodic oxide films of aluminum anodically grown in the solutions of oxalic and/or sulfuric or phosphoric acids have been used for decades as protection and hard coatings or adhesive layers
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We describe a simple nanoporous alumina matrix modification procedure, in which the electrically highly insulating barrier layer at the bottom of the pores is replaced with the gold beds
Summary
Porous anodic oxide films of aluminum anodically grown in the solutions of oxalic and/or sulfuric or phosphoric acids have been used for decades as protection and hard coatings or adhesive layers. The use of anodized aluminum electrodes as support for amperometric sensors is, unexplored due to high resistance of alumina a thin scalloped barrier-oxide layer separated the thick porous one from the metal [23] that is a key problem.
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