Abstract

The Pauli exclusion principle (PEP) can be considered from two aspects. First, it asserts that particles that have half-integer spin (fermions) are described by antisymmetric wave functions, and particles that have integer spin (bosons) are described by symmetric wave functions. It is called spin-statistics connection (SSC). The physical reasons why SSC exists are still unknown. On the other hand, PEP is not reduced to SSC and can be consider from another aspect, according to it, the permutation symmetry of the total wave function can be only of two types: symmetric or antisymmetric. They both belong to one-dimensional representations of the permutation group, while other types of permutation symmetry are forbidden. However, the solution of the Schrödinger equation may have any permutation symmetry. We analyze this second aspect of PEP and demonstrate that proofs of PEP in some wide-spread textbooks on quantum mechanics, basing on the indistinguishability principle, are incorrect. The indistinguishability principle is insensitive to the permutation symmetry of wave function. So, it cannot be used as a criterion for the PEP verification. However, as follows from our analysis of possible scenarios, the permission of states with permutation symmetry more general than symmetric and antisymmetric leads to contradictions with the concepts of particle identity and their independence. Thus, the existence in our Nature particles only in symmetric and antisymmetric permutation states is not accidental, since all symmetry options for the total wave function, except the antisymmetric and symmetric, cannot be realized. From this an important conclusion follows, we may not expect that in future some unknown elementary particles that are not fermions or bosons can be discovered.

Highlights

  • This paper is devoted to one of the fundamental principles of quantum mechanics—the Pauli Exclusion Principle (PEP)

  • With the creation of quantum mechanics, the introduced by Pauli prohibition on the occupation numbers of electron system was supplemented by the prohibition of all types of permutation symmetry of electron wave functions except the antisymmetric ones

  • As was rigorously proved in Ref. [70], the permutation symmetry of noninteracting identical particle system will not change if we introduce the interaction into the system

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Summary

Introduction

This paper is devoted to one of the fundamental principles of quantum mechanics—. the Pauli Exclusion Principle (PEP). First application of the new-born quantum mechanics to many-particle systems was made independently by Heisenberg [6] and Dirac [7] in 1926 In both studies, the authors obtained the Pauli principle as a consequence of the antisymmetry of the Schrödinger wave function and the antisymmetric many-electron wave functions were constructed. With the creation of quantum mechanics, the introduced by Pauli prohibition on the occupation numbers of electron system was supplemented by the prohibition of all types of permutation symmetry of electron wave functions except the antisymmetric ones. Pauli was completely right when he stressed that the spin is a quantum property of electron that cannot be defined in classical physics After this discussion of origin of the spin concept let us return to PEP. These two aspects of PEP will be discussed in two sections

Spin-Statistics
Indistinguishability of Identical Particles and the Symmetrization Postulate
Analysis of the Properties of Identical Particle System Not Obeying PEP
Concluding Remarks
Necessary
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