Abstract

Fundamentals and Transition State Models.The Development of Titanium Enolate Based Aldol Reactions.Boron and Silicon Enolates in Crossed Aldol Reaction.Silver, Gold and Palladium Lewis-Acids.Boron and Silicon Lewis Acids for Mukaiyama Aldol Reactions.Copper Lewis Acids.Tin-promoted Aldol Reactions and Their Applications to Total Syntheses of Natural Products.Zirconium Alkoxides as Lewis Acids.Direct Catalytic Asymmetric Aldol Reaction Using Chiral Metal Complexes.Catalytic Enantioselective Aldol Additions with Chiral Lewis Bases.Amine-Catalyzed Aldol Reactions.Enzyme Catalyzed Aldol Additions.Antibody-Catalyzed Aldol Reactions.The Aldol-Tishchenko Reaction.The Aldol Reaction in Natural Product Synthesis: The Epothilone Story.

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