Abstract

Hazardous substances are considered to be liquids, gases or solids which are of risk for the health and safety of workers and they may be found in almost all workplaces, including in SME’s. Hazardous substances include chemical agents, but also biological ones, such as bacteria, viruses, mould etc. Most chemicals used in the industry present risk for the workers, depending on their physico-chemical properties. Directive 2012/18/EU is the legal act which regulates the chemical substances field within the Member States, regulation dealing with the control of hazards involving dangerous substances which may lead to major accidents. In Romania, Law 59 dated April 2016 on controlling the hazard of major accidents caused by hazardous substances evaluates “hazardous chemicals”, describing the risk for people and regulating concentrations of such substances. By using the commercially available Phast consequence modelling package, within this study were modelled leaks of several chemical substances used in the industry, in order to estimate their hazardous influence extent. The current article is a significant work on modelling of discharge and atmospheric dispersion of hazardous substances using state-of-the-art consequence modelling software. Emergency Response Planning Guidelines (ERPG) are used as reference exposure levels within the present study. Output data of computational modelling are significantly influenced by input parameters. In this regard, the effects of the latter for ensuring robustness of the simulation and for identifying improvements have proven to be necessary.

Highlights

  • Modelling programs existing nowadays are widely used for taking precautions and preventive measures against chemical accidents which may have unwanted consequences upon the workers and surrounding environment

  • The results of the predicted models may be different from the ones which can be generated by such accidents, the limitation of the computational modelling

  • If additional results from real-life experiments cannot be obtained for comparing the values obtained by modelling, such preventive works are trustful since the mathematical models which are implement within commercially available software are validated

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Summary

Introduction

There are used many chemicals which present various risks depending on and whose physical-chemical properties may change drastically with. Such chemicals can be used in industrial processes as solutions with water. In Romania, Law 59 dated April 2016 on controlling the hazard of major accidents caused by hazardous substances evaluates “hazardous chemicals”, describing the risk for people and regulating concentrations of such substances [4, 5]. Modelling program to measure values according to the toxic concentration Emergency Response Planning Guideline (ERPG-1, ERPG-2 and ERPG-3), in case of unexpected leaks of a tank located within an industrial facility and which contains such chemicals [15, 16, 17] This study used PHAST 8.22. modelling program to measure values according to the toxic concentration Emergency Response Planning Guideline (ERPG-1, ERPG-2 and ERPG-3), in case of unexpected leaks of a tank located within an industrial facility and which contains such chemicals [15, 16, 17]

Chemical substances involved
Concentration
Accident modelling
Scenario
Results obtained
Conclusions and final remarks
Full Text
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