Modelling the absorption of nitrogen oxides by ferrous chelate solution in rotating packed bed

Abstract

ABSTRACT With mushrooming growth of coal-based industry, the discharged tail gas containing nitrogen oxides had given significant effect on air quality and people’s health in China. Therefore, more stringent NOx emission standards were proposed. Among many technologies, wet scrubbing technology may be an effective way to solve the above problem, but it was limited by absorption of nitrogen oxides. Therefore, rotating packed bed (RPB) was used to intensify the absorption process of nitrogen oxides by ferrous chelate solution. To speed up its industrialization, a theoretical model was proposed by considering chemical reactions, gas and liquid mass transfer rate, liquid holdup and gas–liquid effective interfacial area. The effects of high gravity factor, gas velocity, gas–liquid ratio, temperature and concentration of ferrous chelate solution on NOx removal efficiency were conducted by model and also compared with experimental results. With high absorption efficiency and small equipment size in RPB, it had a great potential to apply in the absorption other harmful matters.