Modelling of polyurethane foam thermal degradation within annular region subject to fire conditions

Abstract

AbstractNuclear materials are placed in shielded, stainless steel packaging for storage or transport. These drum type packages often employ a layer of foam, honeycomb, wood or cement that is sandwiched between thin metal shells to provide impact and thermal protection during hypothetical accidents, as those prescribed in the Code of Federal Regulations (10 CFR 71·73). The present work discusses the modelling of the thermal degradation of polyurethane (PU) foam within an annular region during an 800°C fire. Measurements and analysis by Hobbs and Lemmon [M. L. Hobbs and G. H. Lemmon: ‘Polyurethane foam response to fire in practical geometries’, Polym. Degrad. Stab., 2004, 84, 183–197.] indicate that at elevated temperatures, PU foam exhibits a two-stage, endothermic degradation. The first stage produces a degraded solid and a combustible gas; the second stage reaction consumes the degraded solid and produces another combustible gas. As a result, during a prolonged fire, a gas filled void develops beside the...