Abstract
To simulate the hydrogen transfer between oil and coal, four hydroaromatic solvents (9,10-dihydrophenanthrene (DHP), tetralin (T), indane (I) and 1,2,3,4-tetrahydroquinoline (THQ)) were reacted with benzyl and phenoxy radicals (resulting from the decomposition of benzylphenylether) in microautoclaves. The reacting mixtures were quantitatively analysed by n.m.r. (400 MHz) and g.c.-m.s. With the help of performance indices, the radical reactions originating from by-products are discussed and an efficiency classification of the four solvents is proposed: DHP > T > THQ > I.
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