Modelling and validation of energy systems with dynamically operated Power to Gas plants for gas-based sector coupling in de-central energy hubs

Abstract

Participants of the COP 26 summit have agreed to limit global temperature rise to 1.5 K by 2050. Out of the many strategies envisaged to meet the targets of COP 26, the ‘Sector Coupling’ process aims to use renewable electricity in residential heating, chemical industry, and transportation sectors. Several studies predict that de-central energy systems will play a significant role in the future. Among the proposed sector coupling strategies in de-central energy systems, the Power to Gas (PtG) process producing chemical energy carriers like Substitute Natural Gas (SNG) from renewable power is gaining acceptance. Numerical models of de-central energy systems are needed to analyse sector coupling under fluctuating renewable energy generation and changing gas demand. This study introduces a numerical model of a decentral energy system that includes a novel methanation concept developed at the Engler Bunte Institut of KIT called 3 Phase Methanation. Here, H2 from electrolysis and CO2 from DAC or other biomass-based sources are passed through a slurry bubble column reactor. The slurry is a suspension of the catalyst in a liquid heat transfer medium where the heat of the reaction is dissipated. The 3-Phase methanation process is modelled in this study using the axial dispersion method. Earlier studies describing experimental campaigns conducted on the pilot plant in KIT have proven that the reactor core is nearly isothermal with stable product gas compositions even if the load changes are instantaneous. In this study, it is shown that the numerical model can replicate the experimental results. Following modelling and validation, the numerical model of the PtG plant is integrated with the other components to simulate the de-central energy system. The simulation results demonstrate the dynamic output of all the components and, in particular, the response provided by the PtG plant. This model can be adapted to simulate sector coupling in future de-central energy systems and analyse aspects like long-term energy storage, GHG minimisation and cost-optimal operation.