Modelling and Optimization of Stability Constants of Cadmium or Zinc with Biological Buffers (DIPSO or TAPS) in Aqueous Solutions by Electrochemical Techniques

Abstract

The complexation behavior of four systems involving cadmium(II) or zinc(II) in aqueous solutions with the biological buffers 3-[N,N-bis(2-hydroxyethyl)amino]-2-hydroxypropanesulfonic acid (DIPSO), and [(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)amino]-1-propanesulfonic acid (TAPS) was studied by direct current polarography (DCP) and glass electrode potentiometry (GEP), at 25.0 ± 0.1 °C and ionic strength 0.1 mol·dm−3 KNO3. Except for the Cd–TAPS system, for which full characterization of the system was possible either by DCP or GEP, full characterization of the other metal-buffer systems (Zn–DIPSO, Zn–TAPS and Cd–DIPSO) was only possible using DCP. For Zn-buffers systems, ZnL+ and $$ {\text{ZnL(OH)}}_{2}^{ - } $$ (where L stands for buffer) were identified. For the Zn–DIPSO system, the overall stability constant values (as log10 β) are 2.1 ± 0.2 and 13.4 ± 0.2, respectively. For the Zn–TAPS system, the overall stability constants values (as log10 β) are 2.4 ± 0.1 and 12.9 ± 0.3, respectively. For the Cd–DIPSO system, the overall stability constants values (as log10 β) of CdL+ and CdL(OH) are 2.9 ± 0.1 and 6.9 ± 0.3, respectively. For the Cd–TAPS system, only the species CdL+ was identified with log10 β = 2.5 ± 0.1.