Abstract

The problem of high desulphurization efficiency of flue gases at high conversion in the solid phase has been investigated. Crystalline NaHCO 3 is fed to a reactor and by its thermal decomposition and highly reactive soda (active soda) is formed. To achieve both high process efficiency (over 95%) and high conversion of the solid (nearly 95%), we took to the two-stage countercurrent flow and to the cyclic operation of the reactor. For this purpose, the bubble assemblage model of Kato and Wen (1969) had been modified for a batch process in the solid phase including the kinetics of the chemical process taking place and the enthalpy balance. Effects of various parameters on the process have been examined by simulation. The model obtained and the results may be applied to the control of the reactor.

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