Abstract

ABSTRACT The shoreline of a potential spill impact area can be divided into units, each with a specific geomorphology. As oil enters each unit, it will (to varying extents) evaporate, dissolve, interact with suspended particles and sink, biodegrade, photo-oxidize, be transported to the next unit, or strand on the shoreline. In the last case, oil will reenter the aquatic system after a given time and again be exposed to these same processes. For modeling purposes, the world's shorelines can be divided into sedimentary beaches and tectonic rocky coasts, varying in wave energy and tidal range. The size of beach sediments can range from very coarse grained (gravels) to very fine grained (silts and clays). Coarse-grained shorelines have higher incoming wave energy than fine-grained areas. Along all coasts, several partitioning components remain relatively constant for medium to light crude oils, e.g., evaporation (30 to 50 percent) and biodegradation/photo-oxidation (0 to 5 percent). Others may vary substantially. For instance, sedimentation may reach 10 to 20 percent in fine-grained estuaries, but only 0 to 2 percent along high energy coasts having very coarse-grained bottom sediments. Similarly, along sandy beaches the stranding of oil along the shoreline may reach 25 to 35 percent, as compared to only 1 to 2 percent along steep, rocky coasts. Dissolution, in general, does not vary so radically, being approximately 10 to 15 percent along high-energy rocky coasts, as compared to 5 to 10 percent in sheltered estuaries that do not have the mixing energy to drive additional oil into the water column.

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