Modeling of the transient behaviors of a lithium-ion battery during dynamic cycling

Abstract

In this paper, we report a modeling methodology on the transient behaviors of a lithium-ion battery (LIB) during dynamic cycling. To account for the short time effects of current pulses and rest periods, the nonfaradaic component of the current density transferred through the separator between the positive and negative electrodes is included based on the lumped double-layer capacitance. Two-dimensional modeling is performed to predict the transient behaviors of an LIB cell during dynamic cycling. To validate the modeling approach presented in this work, modeling results for the variations in cell voltage and two-dimensional temperature distribution of the LIB cell as a function of time are compared with the experimental data for constant-current discharge and charge cycles and the Heavy Duty Urban Dynamometer Driving Schedule cycles. The transient behaviors obtained from the modeling agree well with the experimental measurements.