Modeling of the catalytic properties of high-temperature surface insulation in a dissociated carbon dioxide — Nitrogen mixture

Abstract

A model of the heterogeneous catalysis of a dissociated carbon dioxide — nitrogen mixture on high-temperature heat-shield coatings is developed; the model takes into account nonequilibrium adsorption-desorption reactions of nitrogen and oxygen atoms and carbon dioxide molecules and their recombination in the Eley-Rideal reactions. On the basis of a comparison of the calculated heat fluxes in dissociated carbon dioxide with those measured on the VGU-4 plasma generator of the Institute for Problems in Mechanics of the RAS, the parameters of the catalysis model in question are chosen for three modern oxidant-resistant coating materials. The performances of these coatings are compared for the conditions of Mars Miniprobe entry into the Martian atmosphere. Their usability for the entry path considered is shown.