Abstract

A mathematical model is developed to predict continuous adsorption-regeneration cycling of volatile organic compounds (VOCs) on activated carbon fiber cloth (ACFC) at the indoor VOC concentration levels. The adsorption-regeneration model incorporates both the adsorption equilibrium and mass transfer fundamentals. It assumes local equilibrium between the gas-phase and the solid-phase, and axially dispersed-flow, film transfer, and intraparticle transport by surface and pore diffusion. Successful agreement between model simulations and experimental data was obtained and the kinetic properties of the adsorption/regeneration cycling on the ACFC were characterized. For the adsorption process, the film transfer is the dominant factor for mass transfer at low flow rates (45–184 L/min), and the intraparticle mass transfer rate controls over the gas-phase rate as the flow rates increase. The regeneration concentration profiles are most sensitive to the adsorption isotherms at the temperatures of interest, especial...

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